Construction of Bi/BiOI/BiOCl Z-scheme photocatalyst with enhanced tetracycline removal under visible light

Bi/BiOI/BiOCl composite photocatalyst was constructed by one-step stirring approach at ambient environment to remove of tetracycline (TC) antibiotics via photodegradation in aqueous medium. A systematic discussion of the architecture, composition, formation, photochemical performance and photocatalytic activity of Bi/BiOI/BiOCl was carried out. By adjusting the experimental conditions, it was found that the Bi/BiOI/BiOCl photocatalyst obtained by using 0.7 mmol NaBH₄, I/Cl = 5% and reacting for 6 h had the greatest removal performance. Under visible light irradiation, the photocatalytic degradation efficiency of TC reached 90.3% within 60 min, surpassing that of single BiOCl and BiOI. Through the active species removal experiment, it was determined that •O₂^- made a primary contribution to the photocatalytic degradation process. Moreover, the formation of Z-scheme heterojunction in Bi/BiOI/BiOCl was discussed, analyzing the photocatalytic mechanism and TC degradation pathway. The ecological toxicity of TC solution before and after degradation to rice seedlings was preliminarily tested. This study provides an idea for one-step synthesis of bismuth-based composite photocatalysts, with potential applications in the photocatalytic degradation of antibiotics.