Related Experiment Video
Updated: Jul 10, 2025

In Situ Monitoring of Diffusion of Guest Molecules in Porous Media Using Electron Paramagnetic Resonance Imaging
Published on: September 2, 2016
First-passage functionals of Brownian motion in logarithmic potentials and heterogeneous diffusion
1Max Planck Institute for the Physics of Complex Systems, 01187 Dresden, Germany.
Abstract:
We study the statistics of random functionals Z=∫_{0}^{T}[x(t)]^{γ-2}dt, where x(t) is the trajectory of a one-dimensional Brownian motion with diffusion constant D under the effect of a logarithmic potential V(x)=V_{0}ln(x). The trajectory starts from a point x_{0} inside an interval entirely contained in the positive real axis, and the motion is evolved up to the first-exit time T from the interval. We compute explicitly the PDF of Z for γ=0, and its Laplace transform for γ≠0, which can be inverted for particular combinations of γ and V_{0}. Then we consider the dynamics in (0,∞) up to the first-passage time to the origin and obtain the exact distribution for γ>0 and V_{0}>-D. By using a mapping between Brownian motion in logarithmic potentials and heterogeneous diffusion, we extend this result to functionals measured over trajectories generated by x[over ̇](t)=sqrt[2D][x(t)]^{θ}η(t), where θ<1 and η(t) is a Gaussian white noise. We also emphasize how the different interpretations that can be given to the Langevin equation affect the results. Our findings are illustrated by numerical simulations, with good agreement between data and theory.
More Related Videos
06:55Synthesis of Cyclic Polymers and Characterization of Their Diffusive Motion in the Melt State at the Single Molecule Level
Published on: September 26, 2016
11:03An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Related Concept Videos
Diffusion
Passive Diffusion: Overview and Kinetics
When administered orally, drugs establish a substantial concentration gradient between the gastrointestinal (GI) lumen and the bloodstream, expediting...
Behavior of Gas Molecules: Molecular Diffusion, Mean Free Path, and Effusion
Distribution of Molecular Speeds
Maxwell-Boltzmann Distribution: Problem Solving
This distribution function f(v) is defined by saying that the expected number N (v1,v2) of particles with speeds between v1 and v2 is given by
Protein Diffusion in the Membrane