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Updated: Jun 20, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
In situ rapid synthesis of ionic liquid/ionic covalent organic framework composites for CO2 fixation
Zhifeng Xu1, Wenting Wang1, Bowei Chen1
1College of Biological, Chemical Science and Engineering, Jiaxing University, Jiaxing, Zhejiang 314001, China. ygwang8136@zjxu.edu.cn.
Abstract:
IL/ICOF composites were in situ synthesized via a one-pot route in half an hour under ambient conditions for catalytic cycloaddition of CO2 with epoxides into cyclic carbonates. The prepared composites feature a decent CO2 adsorption capacity of 1.63 mmol g-1 at 273 K and 1 bar and exhibit excellent catalytic performance in terms of yield and durability. This work may pave a new way to design and construct functionalized porous organic frameworks as heterogeneous catalysts for CO2 capture and conversion.
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