Potassium permanganate oxidation enhanced by infrared light and its application to natural water

Photocoupled permanganate (PM) is an effective way to enhance the oxidation efficiency of PM, however, the activation of PM by infrared has received little attention. This study aimed to investigate the ability of infrared light to activate PM. When coupled with infrared, the degradation rate of 4-chlorophenol (4-CP) is increased to 3.54 times of PM oxidation alone. The accelerated reaction was due to the formation of vibrationally excited PM by absorbing 3.1 kJ mol^-1 infrared energy, which also leads to the primary reactive intermediates Mn(V/IV) in the reaction system. The infrared coupled PM system also showed 1.14-2.34 times promotion effect on other organic pollutants. Furthermore, solar composed of 45% infrared, coupled PM system showed excellent degradation performance, where the degradation of 4-CP in 10 L of tap water and river water was 68 and 23 times faster than in ultrapure water, respectively. The faster-increased degradation rate in natural waters is mainly due to the abundant inorganic ions, which can stabilize the manganese species, and then has a positive effect on 4-CP degradation. In summary, this work develops a energy-efficient photoactivated PM technology that utilizes infrared and provides new insights into the design of novel sunlight-powered oxidation processes for water treatment.