Related Experiment Video
Updated: Jul 10, 2025
Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Mg assists in modulating the dimensionalities of the anionic frameworks of borates
Qianzhen Zhang1,2, Feixiang Wang1,2, Xifa Long1,2
1Research Center for Crystal Materials, CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry of CAS, 40-1 South Beijing Road, Urumqi 830011, China. yangyun@ms.xjb.ac.cn.
Abstract:
Three Mg-containing borates were obtained by high-temperature spontaneous crystallization. In the (A2O)- or (A2O-MO)-MgO-B2O3 system (A is alkali metal and M is alkaline-earth metal) reported in the ICSD, Li4Mg3SrB12O24 is the first compound that contains one-dimensional infinite anionic chains, and the two examples of the isostructural A2Mg3B16O28 (A = Rb, Cs) exhibit a two-dimensional infinite bilayer structure for the first time, which contributes to the enrichment of the structural chemistry of Mg-containing borates. Besides, the results of comparison and analysis in this system clearly show that Mg not only affects the anionic frameworks of borates to produce low-dimensional structures but, together with the ratio of Ncation/NB, is responsible for the dimensionalities of the anionic frameworks in borates. The optical properties of the three compounds also show that they all have short cutoff edges, and Cs2Mg3B16O28, in particular, could reach the deep-ultraviolet region (<200 nm).
Related Concept Videos
02:42Valence Bond Theory
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
02:51Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
02:42Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
01:09Complexation Equilibria: Factors Influencing Stability of Complexes
02:34Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...