Bamboo-Modulated Helical Carbon Nanotubes for Rechargeable Zn-Air Battery

The high-performance and sustainable electrocatalysts toward oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) are essential for rechargeable Zn-air batteries (ZABs). In this paper, a natural all-components bamboo is provided as the carbon source, and melamine and cobalt chloride are provided as the nitrogen and cobalt sources, respectively. As a result, the unique helical carbon nanotubes (HCNTs) encapsulated cobalt nanoparticles are prepared, which are acted as ORR/OER electrocatalysts to improve ZABs performance. The resultant HCNTs contribute to high ORR/OER activities via exposing more Co─N sites, providing excellent electron conductivity, and facilitating mass transfer of the reactant. The HCNTs assembled rechargeable liquid ZABs showed a maximum output power density of 226 mW cm^-2 and a low voltage gap of 0.85 V for 330 h cycles. The flexible all-solid-state ZABs achieved the maximum power density with 59.4 mW cm^-2 and charge-discharge cycles over 25 h. The density functional theory (DFT) calculations reveal that the increase of Co─N at HCNTs effectively regulates the electronic structure of Co, optimizing the binding affinity of oxygen intermediates and resulting in the low ORR/OER overpotentials. This work paves the way for transforming renewable bamboo biomass into versatile electrocatalysts, which boosts the development of next-generation energy storage and conversion devices.