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Simple Donor-π-Acceptor Compounds Exhibiting Aggregation-Induced Emission as Hidden Fingerprints Detecting Agents
Patrycja Filipek1, Hubert Hellwig2, Agata Szlapa-Kula1
1Institute of Chemistry, Faculty of Mathematics, Physics and Chemistry, University of Silesia, Szkolna 9, 40-007 Katowice, Poland.
Abstract:
Latent fingerprints are a significant carrier of information for a court expert. To detect this type of forensic trace, what is necessary is a method that is easy to use, compact, and versatile. The research aimed to investigate the physicochemical properties of luminescent substances of donor-π-acceptor systems in terms of their potential use in detecting hidden fingerprints. During the research, a group of fluorene compounds consisting of the (-CH=C(CN)(COOR)) moiety was designed and successfully synthesized. The optical, electrochemical, and aggregation-induced emission properties were studied. The aggregation-induced emission of compounds has been studied in the mixture of THF (as a good solvent) and water (as a poor solvent) with different water fractions ranging from 0% to 99%. Due to the molecular structure, substances showed different affinities to organic traces. As a result, it was noticed that all compounds showed the AIE phenomenon, while during tests on latent fingerprints, it was observed that two substances had particularly forward-looking features in this field.

