Holographic Properties of Irgacure 784/PMMA Photopolymer Doped with SiO₂ Nanoparticles

To enhance the holographic properties, one of the main methods is increasing the solubility of the photosensitizer and modifying the components to improve the modulation of the refractive index in the photopolymer. This study provides evidence, through the introduction of a mutual diffusion model, that the incorporation of SiO₂ nanoparticles in photopolymers can effectively enhance the degree of refractive index modulation, consequently achieving the objective of improving the holographic performance of the materials. Different concentrations of SiO₂ nanoparticles have been introduced into highly soluble photosensitizer Irgacure 784 (solubility up to 10wt%)-doped poly-methyl methacrylate (Irgacure 784/PMMA) photopolymers. Holographic measurement experiments have been performed on the prepared samples, and the experiments have demonstrated that the Irgacure 784/PMMA photopolymer doped with 1.0 × 10-3wt% SiO₂ nanoparticles exhibits the highest diffraction efficiency (74.5%), representing an approximate 30% increase in diffraction efficiency as compared to an undoped photopolymer. Finally, we have successfully achieved the recording of real objects on SiO₂/Irgacure 784/PMMA photopolymers, demonstrated by the SiO₂/Irgacure 784/PMMA photopolymer material prepared in this study, which exhibits promising characteristics for holographic storage applications. The strategy of doping nanoparticles (Nps) in Irgacure 784/PMMA photopolymers has also provided a new approach for achieving high-capacity holographic storage in the future.