Effects of dissolved organic carbon on potentially toxic element desorption in stormwater bioretention systems

Stormwater runoff contains dissolved organic carbon (DOC) and potentially toxic elements (PTEs). Interactions between DOC and PTEs can impact PTE speciation and mobility, but are not fully understood. Soil samples were collected from a vegetated bioretention bed to investigate the effects of DOC (0, 15, and 50 mg-C/L) on the desorption of 10 PTEs captured by the soil media: Mn, Fe, Co, Cu, Zn, As, Cd, Sn, Sb, and Pb. In the absence of DOC, the desorbed PTE concentration from bioretention media into the aqueous phase ranking was as follows: Fe > Mn ∼ Zn > Cu > Pb > Sb > As > Co > Sn ∼ Cd. Increased DOC concentrations resulted in a reduction of the soil-water distribution coefficient (K_d) values. The greatest shift in K_d was observed for Cu and lowest for Sb. The PTE sorption capacities were lower for surficial soil samples (lower K_d) compared to the deep soil samples. Overall, the desorbed PTE (average midchannel 55.7 μg/g) fraction accounted for <1.1 % of the total extracted PTEs (5364 μg/g), and while this is a small percentage of the total, this is the fraction that is mobile. The extracted PTE fractions revealed that DOC reduced the organic matter-bound and carbonate-bound fractions. The PTE desorption trends suggest that reducing DOC in stormwater runoff could be an effective measure to mitigate the release of PTEs into the environment.