Degradation of Procion Brilliant Purple H-3R using ultrasound coupled with advanced oxidation processes

The complexity of wastewater matrix poses a challenge for conventional processes especially due to the presence of refractory compounds such as dyes. The present work focuses on utilizing ultrasound-induced cavitation in conjunction with different oxidants such as hydrogen peroxide, Fenton's reagent and potassium persulfate to treat Procion Brilliant Purple H-3R dye containing wastewater. The impact of various operating parameters as pH, frequency, and power on degradation levels has been studied with the aim of optimizing degradation. The optimal conditions for the degradation of Procion Brilliant Purple H-3R were determined as pH of 12, frequency of 22 kHz, and power of 250 W, resulting in a maximum degradation of 70.25%. Combination of a cavitation reactor with hydrogen peroxide, Fenton reagent, and KPS was then applied at optimized conditions, which confirmed a notable enhancement in degradation compared to the only ultrasound based process. Specifically, the degradation extent was 95.99% for combination with H₂O₂ at 0.5 g/L loading, 99.79% for combination with Fenton at H₂O₂/Fe²⁺ ratio of 50:1, and 99.05% for combination with KPS at loading of 0.75 g/L. The kinetic rate constant for the combined approach of US + Fenton was also maximum at 7.47 × 10^-1 L mg^-1 min^-1. Toxicity analysis was conducted on two bacterial strains, Escherichia coli and Staphylococcus aureus, using the wastewater in native form and after treatment. The various processes were evaluated in terms of the cavitational yield and overall treatment cost and it was determined that US + Fenton process is the most efficient treatment method for fully degrading Procion Brilliant Purple H-3R, particularly at larger scales of operation and cost efficiently as demonstrated in the work.