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Updated: Jul 9, 2025

Physical, Chemical and Biological Characterization of Six Biochars Produced for the Remediation of Contaminated Sites
Published on: November 28, 2014
Reduced and oxidized rice straw biochar for hexavalent chromium adsorption: Revisiting the mechanism of adsorption
Amarjeet Dahiya1, Akanksha Bhardwaj2, Archana Rani1
1Department of Chemistry, School of Basic Sciences, Central University of Punjab, VPO Ghudda, Badal Road, Punjab, 151401, India.
Abstract:
Surface oxygen functional groups of biochar were tuned by oxidation and reduction of biochar for establishing Cr(VI) adsorption mechanism. Oxygen functional groups (OFGs) on the surface of leached rice straw biochar (LBC4-6) obtained from pyrolysis at 400, 500 and 600 °C, were oxidized to furnish OBC4-6 using modified Hummer's method. Reduced biochar RBC4-6 were obtained by esterification and NaBH4/I2 reduction of oxidized biochar (OBC4-6). The modified biochar were characterized by increase in O/C and H/C ratio, respectively, in case of OBC4-6 and RBC4-6. The Cr(VI) adsorption by modified biochar LBC4-6, OBC4-6, and RBC4-6 showed optimum conditions of pH 3 and dose 0.1 g/L with a good non-linear fit for Langmuir & Freundlich isotherm. The maximum adsorption (Qm) followed the trend: OBC4 (17.47 mg/g) > RBC4 (15.23) > OBC5 (13.23) > LBC4 (10.23) > RBC5 (9.83) > OBC6 (9.60) > RBC6 (7.24) > LBC5 (6.32) > LBC6 (5.98). The adsorption kinetics for adsorption of Cr(VI) on to modified biochar fits pseudo second order (PSO), Elovich and intraparticle diffusion kinetics, showing a chemisorptions in case of biochar L/O/RBC4-6. The lower temperature modified biochar O/RBC4 show better Cr(VI) adsorption. X-ray Photoelectron Spectroscopy (XPS) studies establish optimum OFGs for reduction of Cr(VI) and chelation of the reduced Cr(III). Adsorption and stripping cycles show the oxidized and reduced biochar as better adsorbents with excellent stripping of Cr up to >98 % upon desorption with 1 M NaOH.
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