A comparative study of programs to predict direct photolysis rates in wastewater systems

A wide range of contaminants of emerging concern (CECs) are known to photodegrade in the surface layers of natural waters and wastewater systems. Computer programs such as GCSolar, ABIWAS, APEX, EXAMS and WASP model the direct photolysis rates and half-lives of CECs, usually as a function of the solar irradiance, water molar light extinction, chemical molar light absorption and reaction quantum yield. These programs have been used extensively for studies in natural water systems in the northern hemisphere. However, their applicability to wastewater treatment systems such as waste stabilisation ponds and/or southern hemisphere conditions is not well studied. Here we present a comparative review of the major software used and their potential applicability to predicting direct photolysis rates and half-lives in wastewater. The newer equivalent monochromatic wavelength, approach, which enables the approximation of polychromatic photodegradation via a monochromatic wavelength is also discussed. Current software appears to be less suitable for modelling photodegradation in wastewater systems in the southern hemisphere than the northern hemisphere as their internal databases are based on data from natural waters in the northern hemisphere. This may be because there have been few attempts to model CEC photolysis in wastewater systems, particularly in the southern hemisphere. This indicates that either new software needs to be developed, or these programs need to be updated with data on wastewater matrices and/or the southern hemisphere. We anticipate this review will promote the adaptation of these programs as tools to further the understanding CEC photodegradation in wastewater treatment plants.