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Published on: November 11, 2013
Hollow Structure Co1-xS/3D-Ti3C2Tx MXene Composite for Separator Modification of Lithium-Sulfur Batteries
Tianjiao Zhu1, Dong Chen2, Yangyang Mao1
1School of Energy and Power Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Abstract:
The commercial application of lithium-sulfur (Li-S) batteries has faced obstacles, including challenges related to low sulfur utilization, structural degradation resulting from electrode volume expansion, and migration of polysulfide lithium (LiPSs). Herein, Co1-xS/3D-Ti3C2Tx composites with three-dimensional (3D) multilayered structures are used as separator modification materials for Li-S batteries to solve these problems. The multilevel layered structure of Co1-xS/3D-Ti3C2Tx establishes an efficient electron and Li+ transfer path, alleviates the volume change during the battery charge-discharge process, and enhances the stability of the structure. In addition, the battery assembled with the modified separator shows excellent discharge capacity and cycle stability at 0.5 C and could maintain a high discharge capacity after 500 cycles. This work provides a method for designing highly dispersed metal sulfide nanoparticles on MXenes and extends the application of MXenes-based composites in electrochemical energy storage.
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