Synthesis, spectroscopy, band gap energy and electrical conductivity of poly(dopamine-co-aniline) copolymer

Copolymerization is used to improve the solubility and processability of polymers and copolymers includes the individual properties of homopolymer. In this study, the poly(dopamine-co-aniline) (poly(DA-co-ANI) copolymer was synthesized and the UV-vis. absorption, optical band gap energy, fluorescence, FT-IR, SEM-EDS, MALDI-TOF-MS, XRD and electrical conductivity have been investigated. The obtained results for the poly(DA-co-ANI) copolymer were compared with the PDA and PANI homopolymers. It was observed that the poly(DA-co-ANI copolymer is soluble easily in NMP and DMF solvents. The optical band gap energy of the poly(DA-co-ANI) copolymer film were calculated. as 1.00 eV with favorable indirect transition. The poly(DA-co-ANI) copolymer showed the FL emission maximum bands at 390 and 533 nm wavelengths. It was observed from the SEM images that the poly(DA-co-ANI) has 0-1500 nm crystalline rectangular particles prepared in acidic media and 0-600 nm amorphous particles prepared in basic media. The electrical conductivity of the poly(DA-co-ANI) was 1.35 × 10^-6 S/cm. In the MALDI-TOF-MS measurements, the number-average molecular weight of the copolymer was found as 2628 Da with a distribution up to 5500 Da. The poly(DA-co-ANI) copolymer, soluble in NMP and DMF solvents and with a low optical band gap energy can be utilized as optical, fluorescent, and semi-conductive material in biomedical applications.