Emerging iron-based mesoporous materials for adsorptive removal of pollutants: Mechanism, optimization, challenges,
Md Aminul Islam1, Mazen K Nazal2, Michael J Angove3
1Applied Research Center for Environment and Marine Studies (ARCEMS), Research Institute, King Fahd University of Petroleum and Minerals (KFUPM), Dhahran, 31261, Saudi Arabia; Division of Chemistry, Department of Arts and Sciences, Faculty of Engineering, Ahsanullah University of Science and Technology (AUST), 14 1 & 142, Love Road, Tejgaon Industrial Area, Dhaka, 1208, Bangladesh.
Abstract:
Iron-based materials (IBMs) have shown promise as adsorbents due to their unique physicochemical properties. This review provides an overview of the different types of IBMs, their synthesis methods, and their properties. Results found in the adsorption of emerging contaminants to a wide range of IBMs are discussed. The IBMs used were evaluated in terms of their maximum uptake capacity, with special consideration given to environmental conditions such as contact time, solution pH, initial pollutant concentration, etc. The adsorption mechanisms of pollutants are discussed taking into account the results of kinetic, isotherm, thermodynamic studies, surface complexation modelling (SCM), and available spectroscopic data. A current overview of molecular modeling and simulation studies related to density functional theory (DFT), surface response methodology (RSM), and artificial neural network (ANN) is presented. In addition, the reusability and suitability of IBMs in real wastewater treatment is shown. The review concludes with the strengths and weaknesses of current research and suggests ideas for future research that will improve our ability to remove contaminants from real wastewater streams.
