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![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Organic Photoredox Reactions in Two-Molecule Photoredox System
1Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui, 910-8507, Japan.
Abstract:
Using our recent relevant results, this account shows the featured reactivities of two-molecule photoredox systems compared to one-molecule photoredox systems. The low efficiency of electron transfer processes, such as photoinduced and back-electron transfer, in the two-molecule photoredox system, furnishes unique products through different pathways. The facile replacement of photoredox catalysts with appropriate oxidation/reduction potentials in this system provides valuable insights into photoredox reactions.
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