10-Valence-Electron C≡O and the 14-VE C≡Pt: Two Triple-Bonded Isoelectronic Families Differing by a dδ⁴ Ring

10-VE A≡A' Diatomics, such as N≡N, C≡O, etc., have a strong σ²π⁴ triple bond plus a lone pair at each end. In our studies on 14-VE A≡B systems, such as C≡Pt, we find a similar bonding system plus a (5dδ)⁴ ring. Here, the A atom belongs to groups 13-17 and the B atom to groups 7-11. Also the BB' combinations, triatomics, such as PtCO or DsCO or uranyl, and longer chains, such as AuCN and [NC-Au-CN]^-, are discussed. The δ ring directly contributes to nuclear quadrupole coupling constants, and DFT calculations using the BH and H or mPW1K functionals reproduce the experimental trends of the NQCC.