Surface Reconstruction of a Perovskite Film by an Organic Salt for High-Performance Solar Cells with Improved...

Organic-inorganic lead halide perovskites have undergone tremendous development due to their excellent optoelectrical properties, achieving exceptional photovoltaic performance up to over 25%. The interface engineering method has a significant role in further improving the perovskite solar cell performance to its limit. Herein, we fabricated a modified GA_0.07MA_0.93PbI₃ perovskite film using the organic amine small molecule 3-(aminomethyl)pyridine (3AP), which increased the grain sizes and crystallinity through the modulated melting process as well as reacted with the surface component, especially the defect site of the PbI₆ octahedral layer, resulting in a high-quality perovskite film. The perovskite films without (pristine) and with toluene were also fabricated to prove the significant role of the 3AP organic molecule. The 3AP-modified GA_0.07MA_0.93PbI₃ perovskite film exhibits a long carrier lifetime and suppresses the charge recombination loss, resulting in an increased fill factor (FF) of 75.66% and a power conversion efficiency (PCE) of 17.28%, which are higher than those of pristine (FF, 66.36%; PCE, 14.06%) and toluene-treated perovskite devices (FF, 72.40%; PCE, 16.84%). More importantly, the 3AP-modified perovskite device shows remarkable environmental stability to the ambient conditions, with the PCE retaining 92% of the initial PCE for over 1000 h under ambient conditions.