Durability of SrTiO₃-TiO₂ eutectic composite as a photoanode for photoelectrochemical water splitting

The idea of employing sunlight - a virtually inexhaustible source of energy - to catalyze various chemical reactions or generate electrical current is intensively studied nowadays. Here, we describe a method for testing photoelectrochemical (PEC) stability developed using the example of photoanodes from an SrTiO₃-TiO₂ eutectic composite. Eutectic composite stability measurements were carried out in long-term cycles: 0.5, 1, 2, 5, 10, 20 and 50 h of constant electrode operation (total of 88.5 h). After each cycle, cyclic voltammetry, electrochemical impedance spectroscopy, reflectance, roughness, SEM/EDS microstructure analysis and the content of Sr and Ti ions in the applied electrolyte solution were examined. The initial value of the photocurrent density was 1.95 mA cm^-2 at a potential of 1.5 V vs. Ag/AgCl in a pH 2 electrolyte environment and under 6 suns of illumination it increased almost four times, reaching 7.22 mA cm^-2 after a total of 88.5 h of PEC stability cycles. Due to the better catalytic properties of TiO₂, this phase degrades faster, causing an increase in the roughness of the electrode surface. At the same time, reflectance of the photoanode active layer dropped from around 35% to 15%. The investigated method of PEC material testing can be applied in areas beyond photoelectrochemical water splitting, such as chemistry, photovoltaics, sensing and others.