Preparation of polylactic acid (PLA) films plasticized with a renewable and natural Liquidambar Orientalis oil

Polylactic acid (PLA) is a brittle biodegradable thermoplastic due to its relatively high glass transition temperature (T_g ∼ 60 °C). This T_g limits the using of PLA in flexible applications, for example packaging films. In this study, it has been shown for the first time that the Liquidambar Orientalis (LO) oil as a nontoxic, environmentally friendly, and green additive can be successfully used as a natural, renewable, and sustainable plasticizer to produce flexible PLA parts and improve its thermal and physical properties and application potential. Natural oil obtained from Liquidambar Orientalis tree was introduced into PLA (as 10, 20, and 30 phr) by melt compounding (MC) and solution mixing (SM) methods. Effect of LO oil amount on the glass transition temperature, melt and cold crystallization behaviors, and degree of crystallinity values of samples were determined with differential scanning calorimetry (DSC). In addition, solid state viscoelastic properties of PLA films were also characterized with dynamic mechanical analysis (DMA) tests. Results showed that LO oil significantly reduced the T_g and storage modulus (E') value of PLA and LO oil showed an excellent plasticizing effect for PLA due to reducing strong hydrogen bonds and secondary interactions between PLA chains.