Performance of field demonstration nanoscale zero-valent iron in groundwater remediation: A review

Nanoscale zero-valent iron (nZVI) has gained widespread usage in groundwater remediation due to its exceptional reactivity. Since its initial deployment in field demonstrations in 2001, nZVI has proven to be an effective nanomaterial for addressing groundwater contaminants. Subsequent research has highlighted the versatility of nZVI, showcasing its potential to overcome critical limitations associated with conventional remediation technologies. The effectiveness of nZVI in remediation varies, contingent on factors such as the type of nZVI, contaminant nature, site conditions, and injection methodologies employed. This review aims to present a comprehensive progress report on the field application of nZVI spanning 22 years across eight countries. Drawing from a database encompassing 32 pilot or full-scale remediation sites, the study delineates the various types of nZVI, modification methods, demonstration sites, and primary contaminants targeted in field tests. Specific attention is given to the application effects and mechanisms of unmodified nZVI, Pd, surfactants, and carbon-modified nZVI in diverse field demonstrations. An analysis of the key factors influencing their performance is provided, and potential future applications of nZVI in groundwater remediation are discussed.