Effects of thermal treatment on the characteristics of pulp mill residue

In this study, the effects of thermal treatment at moderately low temperatures (T_max: 525 °C) on the composition and properties of two distinct green liquor dregs (GLD) samples from two different pulp mills were investigated. This in-depth characterization was conducted with the aim of enabling the use of GLD as raw materials in cementitious applications (e.g., alkali-activated binders). The elemental composition of the GLD samples primarily comprised Ca, Mg, S, Na, and Mn. Analysis using x-ray diffractometry, an electron probe microanalyzer, and scanning electron microscopy revealed that calcite was the main crystalline phase, whereas layered double hydroxides with varying compositions constituted the primary amorphous phase. Characterization through Fourier-transform infrared spectroscopy and thermogravimetric analysis coupled with mass spectrometer analysis, indicated the loss of water and carbon during thermal treatment. Total organic carbon analysis showed that most of the removed carbon was organic, despite some remaining after thermal treatment at 525 °C. A leaching test was conducted to quantify the soluble Ca, Mg, Na, and K content, as well as pH variations. Overall, the findings suggest that thermal treatment enhances the potential of GLD samples for use in binder materials in the construction sector.