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The Entropy of van der Waals Fluid

Yanhua Lei1, Xiongliang Wang2, Huapeng Sun1

  • 1Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications, School of Chemistry and Environmental Science, Xiangnan University, Chenzhou, Hunan Province, 423000, China.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|December 12, 2023
PubMed
Summary

This study derives thermodynamic state functions using the van der Waals equation in 2D and 3D spaces. While heat capacities differ from ideal gases, adsorbate entropy shows linear correlations with gas and liquid phases.

Keywords:
Adsorbate entropyReal gasReference stateStatistical thermodynamicsSurface chemistry

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