The synergistic effect of oxidant-peroxide coupling systems for water and wastewater treatments

With the growing complexity and severity of water pollution, it has become increasingly challenging to effectively remove contaminants or inactivate microorganisms just by traditional chemical oxidants such as O₃, chlorine, Fe(VI) and Mn(VII). Up till now, numerous studies have indicated that these oxidants in combination with peroxides (i.e., hydrogen peroxide (H₂O₂), peroxymonosulfate (PMS), peracetic acid (PAA) and periodate (PI)) exhibited excellent synergistic oxidation. This paper provided a comprehensive review on the combination of aforementioned oxidant-peroxide applied in water and wastewater treatments. From one aspect, the paper thoroughly elucidated the synergy mechanism of each oxidant-peroxide combination in turn. Among these combinations, H₂O₂ or PMS generally performed as the activator of four traditional oxidants above to accelerate reactive species generation and therein various reaction mechanisms, including electron transfer, O atom abstraction and oxo ligand substitution, were involved. In addition, although neither PAA nor PI was able to directly activate Fe(VI) and Mn(VII), they could act as the stabilizer of intermediate reactive iron/manganese species to improve the latter utilization efficiency. From another aspect, this paper summarized the influence of water quality parameters, such as pH, inorganic ions and natural organic matter (NOM), on the oxidation performance of most combined systems. Finally, this paper highlighted knowledge gaps and identified areas that require further research.