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Anion-π catalysis on carbon allotropes.

M Ángeles Gutiérrez López1, Mei-Ling Tan1, Giacomo Renno1

  • 1Department of Organic Chemistry, University of Geneva, Geneva, Switzerland.

Beilstein Journal of Organic Chemistry
|December 20, 2023
PubMed
Summary

Anion-π catalysis utilizes π-acidic carbon materials to stabilize anionic transition states. This method, particularly effective with polarizable carbon allotropes, shows promise for advancing organic synthesis through enhanced catalytic activity.

Keywords:
Diels–Alder reactionsanion–π interactionsautocatalysiscarbon nanotubescatalysiselectric-field-induced catalysiselectromicrofluidicsenolate additionether cyclizationsfullerenes

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