Microporous nitrogen-rich biomass derived anode catalyst in clay membrane MFC for kitchen wastewater treatment

Microbial fuel cells (MFC) have emerged as a sustainable wastewater treatment technique that offers simultaneous energy generation; however, the high cost of electrodes and their reduced catalytic activity have hindered their widespread adoption. To overcome this, an activated carbon synthesised from Areca nut husk was coated on different anodes viz. Carbon cloth and Stainless Steel (SS) mesh. Activated carbon was found to be highly porous with a carbon content of 85.39%, and a surface area of 767.98 m²/g, and was found to be amorphous with a high degree of graphitic structure. The electrical conductivities of the catalyst-coated SS mesh and carbon cloth were comparable, and the performance of the MFC was studied using both electrodes as anodes. A batch MFC with modified SS mesh as anode exhibited the highest power density of 155.35 mW/m³ in synthetic wastewater and 101.68 mW/m³ in kitchen wastewater, with COD removal efficiencies of 95.32% and 95.24%, respectively. In a continuous mode, the MFC delivered a maximum current density and power of 52.38 mA/m² and 21.60 mW, respectively, with a maximum COD removal efficiency of 80.70% for an HRT of 20 hrs. These findings underscore the viability of using biomass-derived activated carbon as an anode catalyst in both batch and continuous modes of MFC.