Large-Area Rewritable Paper Based on Polyurethane Inverse Photonic Glass with Durable High-Resolution Information...

To alleviate the negative effects of resource waste and environmental pollution caused by the excessive use of paper, technologies for rewritable paper have received widespread attention and in-depth research. Despite the growing interest in rewritable paper, meeting the requirements of large-scale preparation, long-lasting information storage time, high reversibility, and good environmental stability remains a huge challenge for this technology. This study developed a solvent-responsive copolymerized polyurethane-based rewritable paper with an inverse photonic glass structure (co-PUIPG paper). Comprehensive writing modes, including handwriting, spraying, and printing, were realized by using the swelling effect of different solvents and the local force field formed by capillary force to control the deformation degree of the inverse photonic glass structure. Co-PUIPG paper can persistently store high-resolution information and has a green and environmentally friendly "write-erase" method. Meanwhile, it exhibits good rewritability, as well as high mechanical strength and exceptional resistance to environmental factors, such as friction, high temperature, and sunlight. Because the spraying method can prepare templates quickly and extensively and polyurethane materials are economical, co-PUIPG rewritable paper possesses great potential as a substitute for commercial fiber paper and its industrialization is full of great possibilities.