Recent progress of heterogeneous catalysts for transfer hydrogenation under the background of carbon neutrality
Guangyu Chen1, Jun Ma1,2, Wanbing Gong1
1National Synchrotron Radiation Laboratory, School of Nuclear Science and Technology, Hefei National Research Center for Physical Sciences at the Microscale, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China. yjxiong@ustc.edu.cn.
Abstract:
Under the background of carbon neutrality, the direct conversion of greenhouse CO2 to high value added fuels and chemicals is becoming an important and promising technology. Among them, the generation of liquid C1 products (formic acid and methanol) has made great progress; nevertheless, it encounters the problem of how to use it efficiently to solve the overcapacity issue. In this review, we suggest that the catalytic transfer hydrogenation using formic acid and methanol as the hydrogen sources is a critical and potential route for the substitution for the fossil fuel-derived H2 to generate essential bulk and fine chemicals. We mainly focus on summarizing the recent progress of heterogeneous catalysts in such reactions, including thermal- and photo-catalytic processes. Finally, we also propose some challenges and opportunities for this development.
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