X-ray/gamma radiation shielding properties of zinc ferrite nanoparticles synthesised via solution combustion method

Zinc ferrite (ZnFe2O4) nanoparticles were synthesised via solution combustion method using urea as a fuel. The synthesised samples were characterised with various techniques. The cubic structure with Fd-3 m space group is confirmed by Powder X-ray Diffraction and Bragg's reflection. The crystallite size estimated from Scherrer's method was found to be 40 nm. The agglomerated irregular shape and sized surface morphology was confirmed by Scanning Electron Microscopy image. The direct energy band gap determined from Wood and Tauc's relation was found to be 5.25 eV. Using a NaI (Tl) detector and multi-channel analyser, the described sample was examined for X-ray and gamma ray shielding characteristics in the energy range of 0.081-1.332 MeV. The measured shielding values are in good agreement with the theory, however below 356 keV, there is a little variation of up to 10%. The current work offers up new possibilities for using this simple, affordable, effective and low temperature approach to create nanomaterials for X-ray and gamma ray shielding.