Enabling Long-Life Aqueous Organic Redox Flow Batteries with a Highly Stable, Low Redox Potential Phenazine Anolyte

Aqueous organic redox flow batteries (AORFBs) are considered a promising energy storage technology due to the sustainability and designability of organic active molecules. Despite this, most of AORFBs suffer from limited stability and low voltage because of the chemical instability and high redox potential of organic molecules in anolyte. Herein, we propose a new phenazine derivative, 4,4'-(phenazine-2,3-diylbis(oxy))dibutyric acid (2,3-O-DBAP), as a water-soluble and chemically stable anodic active molecules. By combining calculations and experiments, we demonstrate that 2,3-O-DBAP exhibits a higher solubility, a lower redox potential (-0.699 V vs SHE), and greater chemical stability than other O-DBAP isomers. Then, we demonstrate a long-lasting flow cell with an average discharge voltage of 1.12 V, a low fade rate of 0.0127%, and a lifespan of 62 days at pH 14 using 2,3-O-DBAP paired with ferri/ferrocyanide. The negligible self-discharge behavior also verifies the high stability of 2,3-O-DBAP. These results highlight the importance of molecular engineering for AORFBs.