Recent progress in chromium removal from wastewater using covalent organic frameworks - A review

Covalent organic frameworks (COFs) offer a pivotal solution to urgently address heavy metal removal from wastewater due to their exceptional attributes such as high adsorption capacity, tunable porosity, controllable energy band structures, superior photocatalytic performance, and high stability-reusability. Despite these advantages, COFs encounter certain challenges, including inefficient utilization of visible light, rapid recombination of photogenerated carriers, and limited access to active sites due to close stacking. To enhance the photocatalytic and adsorptive performance of COF-based catalysts, various modification strategies have been reported, with a particular focus on molecular design, structural regulation, and heterostructure engineering. This review comprehensively explores recent advancements in COF-based photocatalytic and adsorptive materials for chromium removal from wastewater, addressing kinetics, mechanisms, and key influencing factors. Additionally, it sheds light on the influence of chemical composition and functional groups of COFs on the efficiency of hexavalent chromium [Cr (VI)] removal.