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Spin systems where the difference in chemical shifts of the coupled nuclei is greater than ten times J are called first-order spin systems. These nuclei are weakly coupled, and their chemical shifts and coupling constant can generally be estimated from the well-separated signals in the spectrum.
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Atomic Nuclei: Nuclear Spin State Overview01:03

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NMR-active nuclei have energy levels called 'spin states' that are associated with the orientations of their nuclear magnetic moments. In the absence of a magnetic field, the nuclear magnetic moments are randomly oriented, and the spin states are degenerate. When an external magnetic field is applied, the spin states have only 2 + 1 orientations available to them. A proton with = ½ has two available orientations. Similarly, for a quadrupolar nucleus with a nuclear spin value of...
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The spin state of an NMR-active nucleus can have a slight effect on its immediate electronic environment. This effect propagates through the intervening bonds and affects the electronic environments of NMR-active nuclei up to three bonds away; occasionally, even farther. This phenomenon is called spin–spin coupling or J-coupling. Coupling interactions are mutual and result in small changes in the absorption frequencies of both nuclei involved. While nuclei of the same element are involved...
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The number of nuclear spins aligned in the lower energy state is slightly greater than those in the higher energy state. In the presence of an external magnetic field, as the spins precess at the Larmor frequency, the excess population results in a net magnetization oriented along the z axis. When a pulse or a short burst of radio waves at the Larmor frequency is applied along the x axis, the coupling of frequencies causes resonance and flips the nuclear spins of the excess population from the...
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All atomic nuclei are positively charged. When they have a nonzero spin, they behave like rotating charges. As a consequence of their charge and spin, these nuclei generate a magnetic field (B). This, in turn, gives rise to a magnetic moment (μ), which is randomly oriented in the absence of an external magnetic field. When an external magnetic field (B0) is applied, the magnetic moment vectors can align with the field or against it in 2 + 1 orientations. A hydrogen nucleus, which is just a...
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Quantifying Mixing using Magnetic Resonance Imaging
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Quantifying the Magnetic Interactions Governing Chiral Spin Textures Using Deep Neural Networks.

Jian Feng Kong1, Yuhua Ren2, M S Nicholas Tey3

  • 1Agency for Science, Technology & Research (A*STAR), Institute of High Performance Computing, Singapore 138632, Singapore.

ACS Applied Materials & Interfaces
|December 29, 2023
PubMed
Summary

Machine learning predicts magnetic interactions from chiral domain images. This approach accelerates the development of nanoscale electronics by offering a high-throughput alternative to traditional methods.

Keywords:
chiral spin texturesmachine learningmagnetic interactionsmagnetic microscopymagnetismneural networkspintronics

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Area of Science:

  • Condensed Matter Physics
  • Materials Science
  • Computational Science

Background:

  • Chiral multilayer films host nanoscale topological spin textures crucial for advanced computing.
  • Conventional methods for quantifying magnetic interactions are often specialized, time-consuming, and resource-intensive.
  • High-throughput imaging of domain configurations offers a potential solution for rapid interaction analysis.

Purpose of the Study:

  • To develop a machine learning (ML)-based approach for simultaneously determining key magnetic interactions (symmetric exchange, chiral exchange, anisotropy) from chiral domain images.
  • To validate the ML model's predictive accuracy and its ability to uncover physical interdependencies between magnetic parameters.
  • To demonstrate the utility of ML-driven techniques as a high-throughput complement to conventional experimental methods.

Main Methods:

  • Development and training of a convolutional neural network (CNN) model using over 10,000 binarized domain images.
  • Simultaneous prediction of symmetric exchange, chiral exchange, and anisotropy parameters from single images.
  • Validation of model predictions against independent experimental measurements.

Main Results:

  • The ML model achieved an R-squared value greater than 0.85 in predicting magnetic interaction parameters.
  • The model independently learned and revealed physical interdependencies between the magnetic parameters.
  • Model predictions on microscopy data showed consistency with established experimental findings.

Conclusions:

  • ML-driven techniques provide a valuable, high-throughput method for determining magnetic interactions in chiral multilayer films.
  • This approach can significantly accelerate the development of materials and devices for nanoscale electronics.
  • The study highlights the potential of ML to streamline complex materials characterization processes.