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Updated: Jul 6, 2025

Quantitative Detection of Trace Explosive Vapors by Programmed Temperature Desorption Gas Chromatography-Electron Capture Detector
Published on: July 25, 2014
Standoff trace explosives vapor detection at meter distances.
Megan K Nims1, Elizabeth H Denis2, Garret L Hart1
1Pacific Northwest National Laboratory, 902 Battelle Boulevard, P.O. Box 999, MSIN P7-50, Richland, WA 99352, USA.
This study shows that atmospheric flow tube-mass spectrometry (AFT-MS) can detect trace explosives vapor at meters away. This noncontact method offers a less invasive approach to security screening.
Area of Science:
- Analytical Chemistry
- Chemical Engineering
- Forensic Science
Background:
- Explosives vapor detection is crucial for security but challenging due to low vapor concentrations.
- Current methods like physical swiping are invasive and may miss trace amounts.
- Noncontact vapor detection offers a less invasive and potentially more sensitive alternative.
Purpose of the Study:
- To demonstrate the capability of atmospheric flow tube-mass spectrometry (AFT-MS) for standoff detection of trace explosives vapor.
- To evaluate the sensitivity and standoff distances achievable with AFT-MS combined with a high-volume air sampler.
- To explore the potential applications of this technology in security screening.
Main Methods:
- Utilized atmospheric flow tube-mass spectrometry (AFT-MS) with a high-volume air sampler.
- Performed standoff detection experiments with explosives vapor sources (RDX, nitroglycerin residue).
- Investigated detection capabilities at various distances and relative to air currents.
Main Results:
- Achieved parts-per-quadrillion sensitivity for explosives vapor detection.
- Demonstrated standoff detection of RDX vapor up to 2.5 meters and residue vapors up to 0.5 meters.
- Confirmed successful detection both upstream and downstream of the vapor source, irrespective of room air currents.
Conclusions:
- AFT-MS with a high-volume sampler enables effective standoff detection of trace explosives vapor.
- The technology offers a sensitive, noncontact method for explosives screening.
- Potential applications include security screening at mail facilities, border crossings, and checkpoints for explosives, drugs, and chemical threats.
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