Characteristics of airborne particles in stone quarrying areas: Human exposure assessment and mitigation

This investigation aims to assess the levels of human exposure to airborne particulate matter (PM) in various locations of a natural stone quarry for the first time based on simultaneous measurements of both PM mass and number concentrations (PMC and PNC). A quarry located in Danang city, Vietnam, considered to be a "hotspot" of air pollution in the city, was selected for detailed investigations. Both PMC and PNC were found to be significantly higher (1.2-6.0 times) within the quarry compared to surrounding areas. Mechanical activities during mining, notably crushing, screening, hauling, and loading stones, contributed to increased emissions of PM in the coarser mode (1-10 μm) compared to the accumulation mode (0.1-1 μm) and thus increased deposition of PM_1-10 in the human upper respiratory tract. In contrast, combustion activities, especially the diesel engine exhaust from various machines and vehicles used in the quarry, resulted in increased emissions of small particles in the accumulation mode that dominated the PNC and in their deposition in the lower respiratory tract. Simultaneous measurements of PNC and PMC revealed that the PM counts were strongly associated with PM deposition in the alveolar region (accounting for ≈ 76% of total PNC of particles less than 10 μm, N₁₀), while the PM mass concentration was a better indicator of the deposition of PM in the head airway region (≈92% of total PMC of PM₁₀). Overall, this study demonstrates the significance of measuring both PNC and PMC to assess PM exposure levels, regional respiratory doses, and potential health effects associated with human exposure to PM generated from stone quarrying activities. The novelty of this work is the integration of real-time mass and number concentrations of PM over the size range from 20 nm to 10 μm to provide insights into respiratory deposited doses of size-fractionated PM among quarry workers.