Synthesis of NiFe-layered double hydroxides using triethanolamine-complexed precursors as oxygen evolution reaction...

The synthesis of highly efficient NiFe-layered double hydroxides (NiFe-LDHs) to catalyze the oxygen evolution reaction (OER) is urgent and challenging. Herein, NiFe-FeCl₃-x and NiFe-FeCl₂-x samples (where FeCl₃ and FeCl₂ represent the Fe sources and x represents the imposed reaction time: 6, 12, and 24 h) were prepared via one-pot hydrothermal synthesis using Fe sources characterized by Fe(III) or Fe(II) valence states. In the presence of triethanolamine, when FeCl₃ was used as the Fe source, pure NiFe-LDH was obtained, whose crystallinity increased with increasing hydrothermal treatment time. In contrast, when FeCl₂ was used as the Fe source, a mixture of NiFe-LDH, Fe₂O₃, and trace amounts of Fe₃O₄ was obtained. The content of NiFe-LDH in the mixture increased under longer hydrothermal treatment and NiFe-FeCl₃-x catalysts exhibited better OER performance than NiFe-FeCl₂-x catalysts. Specifically, NiFe-FeCl₃-6 afforded the highest OER performance with an overpotential of 246.8 mV at 10 mA cm^-2 and a Tafel slope of 46.1 mV dec^-1. Herein, we investigated the effects of the valence state of Fe precursors on the structures and OER activities of the prepared catalysts; the mechanism of NiFe-LDH formation via hydrothermal synthesis in the presence of triethanolamine was also proposed.