Adjusting Li⁺ Solvation Structures via Dipole-Dipole Interaction to Construct Inorganic-Rich Interphase for...

Practical applications of lithium metal batteries are limited by unstable solid electrolyte interphase (SEI) and uncontrollable dendrite Li deposition. Regulating the solvation structure of Li⁺ via modifying electrolyte components enables optimizing the structure of the SEI and realizing dendrite-free Li deposition. In this work, it is found that the ionic-dipole interactions between the electron-deficient B atoms in lithium oxalyldifluoro borate (LiDFOB) and the O atoms in the DME solvent molecule can weaken the interaction between the DME molecule and Li⁺, accelerating the desolvation of Li⁺. On this basis, the ionic-dipole interactions facilitate the entry of abundant anions into the inner solvation sheath of Li⁺, which promotes the formation of inorganic-rich SEI. In addition, the interaction between DFOB^- and DME molecules reduces the highest occupied molecular orbital energy level of DME molecules in electrolytes, which improves the oxidative stability of the electrolytes system. As a result, the Li||Li cells in LiDFOB-containing electrolytes exhibit an excellent cyclability of over 1800 h with a low overpotential of 18.2 mV, and the Li||LiFePO₄ full cells display a high-capacity retention of 93.4% after 100 cycles with a high Coulombic efficiency of 99.3%.