Hydrochromic film for dynamic information storage using cellulose nanofibers and silica nanoparticles

A hydrochromic composite film was fabricated by incorporating silica nanoparticles (SiNPs) with cellulose nanofibers (CNFs). The CNF/SiNP composite film underwent a reversible change in transparency in response to external moisture variation. The CNFs improved the dimensional stability of the CNF/SiNP composite film and induced morphological differences in SiNP agglomerates, which control the water vapor condensation in a porous film. The condensed water in the pores reduced the difference in refractive index over the CNF/SiNP film, enhancing its transparency. The selective transparency of the composite film was challenged by printing CNF/SiNP inks at different composition ratios. The differing susceptibility of the printed patterns to moisture provided selective transparency at specific patterns, which can store dynamic information such as QR or numerical codes by simple water vapor adsorption and desorption.