Cellulose-based bi-layer hydrogel evaporator with a low evaporation enthalpy for efficient solar desalination

Interfacial evaporation through hydrogel-based evaporators is emerging as a sustainable and cost-effective strategy for drinkable water production. Herein, a specially designed bi-layer hydrogel evaporator was fabricated and used for efficient solar water desalination. With cotton linter as cellulose precursor, it was dispersed in a highly concentrated ZnCl₂ (65 %) solution, and cross-linked by epichlorohydrin to prepare cellulose composite hydrogel. After removing inorganic salts by salt-leaching, polyaniline (PANi) with broadband and wide-range light absorption was then integrated into the top surface of hydrogel through in situ polymerization to construct a bi-layer evaporator. As a solar evaporator, the water could be evaporated with a low-energy demand, and the heat from the sunlight could be confined at the interface to achieve efficient water evaporation. Therefore, the hydrogel evaporator demonstrates an optimal water evaporation rate of 3.02 kg m^-2 h^-1 and photothermal conversion efficiency of 89.09 % under 1 sun (1 kW m^-2) irradiation. This work provides new possibilities for efficient solar water purification systems with assured water quality.