Oxidized Cellulose Nanocrystals from Durian Peel Waste by Ammonium Persulfate Oxidation

Cellulose nanocrystals (CNCs) have gained much attention due to their biodegradable, renewable, nontoxic, and inexpensive nanomaterials with some remarkable properties. In this study, cellulose nanocrystals from durian peel waste were isolated by chemical oxidation. This process involved two stages of a chemical process, namely, bleaching followed by oxidation of ammonium persulfate (APS). The impact of process parameters (APS concentrations and oxidation temperatures) on the oxidized CNC was assessed. The properties of CNC were investigated by attenuated total reflection-infrared (ATR-IR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM). ATR-IR results showed that the structure of cellulose did not change during APS oxidation. XRD results indicated that APS oxidation improved the crystallinity index by 103% due to the removal of the amorphous components. The resulting CNC was needlelike in shape and had an average width range of 5.00-7.81 nm, a length range of 114.52-126.83 nm, and an aspect ratio range of 16.76-24.20. From the TGA analysis, the thermal stability was found to increase with increasing oxidation temperature. The optimum conditions for a maximum crystallinity index and the highest thermal stability were obtained at 80°C oxidation with 1 M APS. Therefore, APS oxidation was a remarkable method for increasing the value of durian peel waste into high-value nanocellulose.