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    Area of Science:

    • Spectroscopy
    • Materials Science
    • Nanotechnology

    Background:

    • Diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) is crucial for material analysis.
    • Existing methods often lack the spatial resolution for micro-scale samples.
    • Characterizing small, complex structures requires advanced spectroscopic techniques.

    Purpose of the Study:

    • To develop and validate a cost-effective micro-DRIFTS system.
    • To assess the system's performance on small-area diffuse samples.
    • To enable detailed analysis of micro-scale materials, such as vertically aligned carbon nanotubes.

    Main Methods:

    • Development of a novel micro-diffuse reflectance infrared Fourier transform spectroscopic (micro-DRIFTS) setup.
    • System calibration and performance characterization using standard and target samples.
    • Application of the micro-DRIFTS system to analyze small-area vertically aligned carbon nanotube (VACNT) samples.

    Main Results:

    • The developed micro-DRIFTS system achieves a spatial resolution of approximately 140 µm.
    • Sensitivity levels in the tens of parts per million (ppm) were demonstrated within the 2 µm - 18 µm spectral range.
    • The system successfully measured reflectance from small-area VACNT samples.
    • An uncertainty budget was established, and a method for equating measured reflectance to directional-hemispherical reflectance was presented.

    Conclusions:

    • The low-cost micro-DRIFTS system provides a viable tool for analyzing micro-scale diffuse samples.
    • The system's high spatial resolution and sensitivity are suitable for characterizing nanomaterials like VACNTs.
    • This development advances the capability for detailed spectroscopic analysis of small and complex material structures.