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Updated: Jul 6, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Organocatalyst Supported by a Single-Atom Support Accelerates both Electrodes used in the Chlor-Alkali Industry via
Jiarui Yang1, Chenxi Zhu1, Wen-Hao Li1
1Department of Chemistry, Tsinghua University, Beijing, 100084, China.
Abstract:
Consuming one of the largest amount of electricity, the chlor-alkali industry supplies basic chemicals for society, which mainly consists of two reactions, hydrogen evolution (HER) and chlorine evolution reaction (CER). Till now, the state-of-the-art catalyst applied in this field is still the dimensional stable anode (DSA), which consumes a large amount of noble metal of Ru and Ir. It is thus necessary to develop new types of catalysts. In this study, an organocatalyst anchored on the single-atom support (SAS) is put forward. It exhibits high catalytic efficiency towards both HER and CER with an overpotential of 21 mV and 20 mV at 10 mA cm-2 . With this catalyst on both electrodes, the energy consumption is cut down by 1.2 % compared with the commercial system under industrial conditions. Based on this novel catalyst and the high activity, the mechanism of modifying non-covalent interaction is demonstrated to be reliable for the catalyst's design. This work not only provides efficient catalysts for the chlor-alkali industry but also points out that the SACs can also act as support, providing new twists for the development of SACs and organic molecules in the next step.
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