Photocatalytic Activity and Self-Cleaning Effect of Coating Mortars with TiO₂ Added: Practical Cases in Warm...

In this study, the photocatalytic activity of coating mortars with synthetized and commercial TiO₂ nanoparticles added has been evaluated at 2, 3 and 5% by weight of cement by calculating the degradation efficiency of methyl orange and red wine dyes exposed to both visible-light and UV radiation; also, the self-cleaning effect of coatings exposed to weather conditions (warm sub-humid climate) was assessed. TiO₂ nanoparticles were synthesized via the sol-gel method to a low synthesis temperature and characterized via X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM). The results show synthesized TiO₂ particles in anatase phase with a crystallite size of 14.69 nm, and hemispherical particles with sizes of submicron order. The addition percentage with the best performance in the coating mortars was 3%, with both commercial and synthesized TiO₂; however, coating mortars with synthesized TiO₂ exhibited the highest degradation efficiency for both dyes when they were exposed to visible light, while mortars with commercial TiO₂ exhibited the highest degradation efficiency when exposed to UV radiation. In addition, in coating mortars with synthesized TiO₂, the self-cleaning effect was evident from the beginning of exposure to weather, reaching the largest dye-free surface at the end of exposure. The compressive strength increased significantly in mortars with TiO₂ addition.