A High Temperature Harvestorer Based on a Photovoltaic Cell and an Oxygen Ion Battery

Hybrid devices for combined energy harvesting and storage, i.e., harvestorers, are attractive solutions for powering small autonomous devices (e.g., "smart appliances", Internet of things nodes), which are ever more prominent as the digitalization and technologization of our society progresses. A concept for a high temperature (HT) harvestorer is presented, and the operational characteristics of a prototype device are discussed. It is based on photovoltaic (PV) energy harvesting and HT electrochemical energy storage. The HT-PV cells employ SrTiO₃/La_0.9Sr_0.1CrO_3-δ heterojunctions for energy harvesting and produce photovoltages up to 1 V and photocurrents of several mA cm^-2 upon UV illumination at 350 °C. Electrochemical energy storage is realized by oxygen ion battery (OIB), a device based on mixed ionic and electronic conducting oxide thin film electrodes and an yttria stabilized zirconia electrolyte. The OIB exhibits capacities of up to 11 mC cm^-2 (3 μA h cm^-2) at 0.6 V (350 °C). A prototype harvestorer device was fabricated by integrating an HT-PV and an OIB cell into one device. This harvestorer was operated over several cycles consisting of harvesting and storing energy under illumination, followed by retrieval of the stored energy without illumination. Up to 3.5 mJ cm^-2 (1 μW h cm^-2) was stored with energy efficiencies up to 67%. Approaches for further optimization are discussed.