Hot carbonates deep within the Chicxulub impact structure

Constraining the thermodynamic conditions within an impact structure during and after hypervelocity impacts is extremely challenging due to the transient thermal regimes. This work uses carbonate clumped-isotope thermometry to reconstruct absolute temperatures of impact lithologies within and close to the ∼66 Myr old Chicxulub crater (Yucatán, México). We present stable oxygen (δ¹⁸O), carbon (δ¹³C), and clumped-isotope (Δ₄₇) data for carbonate-bearing impact breccias, impact melt rock, and target lithologies from four drill cores on a transect through the Chicxulub structure from the northern peak ring to the southern proximal ejecta blanket. Clumped isotope-derived temperatures (T(Δ₄₇)) are consistently higher than maximum Late Cretaceous sea surface temperatures (35.5°C), except in the case of Paleogene limestones and melt-poor impact breccias outside of the crater, confirming the influence of burial diagenesis and a widespread and long-lived hydrothermal system. The melt-poor breccia unit outside the crater is overlain by melt-rich impact breccia yielding a much higher T(Δ₄₇) of 111 ± 10°C (1 standard error [SE]), which likely traces the thermal processing of carbonate material during ejection. Finally, T(Δ₄₇) up to 327 ± 33°C (1 SE) is determined for the lower suevite and impact melt rock intervals within the crater. The highest temperatures are related to distinct petrological features associated with decarbonation and rapid back-reaction, in which highly reactive CaO recombines with impact-released CO₂ to form secondary CaCO₃ phases. These observations have important climatic implications for the Cretaceous-Paleogene mass extinction event, as current numerical models likely overestimate the release of CO₂ from the Chicxulub impact event.