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Sacrificial-Hydroxamate-Enabled Sizable Crystallization of Scandium Carboxylate Metal-Organic Frameworks
Wenjing Wu1, Wenlei Tang2, Zhen-Wu Shao1
1School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Inorganic Chemistry
|January 12, 2024
Abstract:
Starting from labile hydroxamic acid ligands that are strong chelators, here, we implemented a sacrificial modulating strategy to prepare a series of scandium carboxylate metal-organic frameworks. Overcoming conventional syntheses that use excessive carboxylate modulators, the present strategy greatly reduces the organics required and produces large single crystals of several Sc-MOFs for X-ray crystallography.

