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Updated: Jul 5, 2025

Developing Photosensitizer-Cobaloxime Hybrids for Solar-Driven H2 Production in Aqueous Aerobic Conditions
Published on: October 5, 2019
Rational design of triazine-based conjugated polymers with enhanced charge separation ability for photocatalytic
Changzhi Han1, Jiaxin Ma1, Xuan Ai1
1Key Laboratory for Macromolecular Science of Shaanxi Province, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710062, PR China.
Abstract:
Triazine-based conjugated polymers (TCPs) are promising organic catalysts for green H2 production, since their photocatalytic performance can be easily regulated via appropriate molecular design. However, apart from weak absorption of visible light, weak charge separation and transport abilities also considerably restrict the photocatalytic performance of TCPs. Herein, we report two novel TCP photocatalysts with donor-acceptor (D-A) and donor-π-acceptor (D-π-A) structures using dibenzo[g,p]chrysene (Dc), thiophene (T), and 2,4,6-triphenyl-1,3,5-triazine (Tz) as the donor, π-spacer, and acceptor, respectively. Compared to Dc-Tz with a D-A structure, Dc-T-Tz exhibits a broader light absorption edge and more efficient charge separation and transmission due to its D-π-A structure and strong dipole effect. These properties enable Dc-T-Tz to display a prominent H2 production rate of 45.13 mmol h-1 g-1 under ultraviolet-visible (UV-Vis) light (λ > 300 nm). Therefore, Dc-T-Tz represents state-of-the-art TCP photocatalysts to date.
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