Related Experiment Video
Updated: Jul 5, 2025

Two-way Valorization of Blast Furnace Slag: Synthesis of Precipitated Calcium Carbonate and Zeolitic Heavy Metal Adsorbent
Published on: February 21, 2017
New Process for Na2CO3 Production from Na2SO4 Based on Modeling the Na2SO4-(NH4)2SO4-MEA-MEG-H2O System
Binghui Li1, Edouard Asselin1, Zhibao Li2
1Department of Materials Engineering, The University of British Columbia, 309-6350 Stores Road, Vancouver, British Columbia V6T 1Z4, Canada.
Abstract:
Alternative means for soda ash (Na2CO3) production from sodium sulfate (Na2SO4) are needed due to the intensive consumption of energy in the conventional Mirabilite-Solvay process (MSP). We demonstrate a new process to produce soda ash using sodium sulfate as a feed material. The new process relies on the antisolvent crystallization of unreacted Na2SO4 to separate it from soluble (NH4)2SO4 in a mixed monoethanolamine (MEA) and monoethylene glycol (MEG) solution. To develop the process, the solubilities of Na2SO4 and (NH4)2SO4 solids in aqueous mixed MEA-MEG solutions were first measured and then modeled using regressed paired-ion interactions from the electrolyte nonrandom two-liquid (E-NRTL) model. Anhydrous dense soda ash with a bulk density of up to 1146 kg/m3 was obtained when the concentrated Na2SO4 brines reacted with CO2 and NH3.
Related Concept Videos
Weak Base Solutions
Chemical Equilibria: Systematic Approach to Equilibrium Calculations
The first step is to identify all the chemical reactions involved, The...
Nucleophilic Substitution Reactions
In 1896, the German chemist Paul Walden discovered that he could interconvert pure enantiomeric (+) and (-) malic acids through a series of reactions. This conversion suggested the involvement of optical inversion during the substitution reaction. Further, in 1930, Sir Christopher Ingold described for the first time two different forms of nucleophilic substitution reactions, which are known as SN1 (nucleophilic substitution unimolecular) and SN2 (nucleophilic substitution...
Titration of Polyprotic Base with a Strong Acid
Titration Calculations: Weak Acid - Strong Base
For the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH, the reaction can be represented as:
Preparation of Carboxylic Acids: Hydrolysis of Nitriles

