Related Experiment Video
Updated: Jul 5, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Electrocatalytic Reduction of CO2 and H2O with Zn(II) Complexes Through Metal-Ligand Cooperation
Somayeh Norouziyanlakvan1, Patrick Berro1, Gyandshwar Kumar Rao2
1Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada.
Abstract:
Air and water-stable zinc (II) complexes of neutral pincer bis(diphenylphosphino)-2,6-di(amino)pyridine ("PN3P") ligands are reported. These compounds, [Zn(κ2-2,6-{Ph2PNR}2(NC5H3))Br2] (R=Me, 1; R=H, 2), were shown to be capable of electrocatalytic reduction of CO2 at -2.3 V vs. Fc+/0 to selectively yield CO in mixed water/acetonitrile solutions. These complexes also electrocatalytically generate H2 from water in acetonitrile solutions, at the same potential, with Faradaic efficiencies of up to 90 %. DFT computations support a proposed mechanism involving the first reduction of 1 or 2 occurring at the PN3P ligand. Furthermore, computational analysis suggested a mechanism involving metal-ligand cooperation of a Lewis acidic Zn(II) and a basic ligand.
Related Concept Videos
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Formation of Complex Ions
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
Reduction of Alkenes: Catalytic Hydrogenation
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
Aldehydes and Ketones to Alkanes: Wolff–Kishner Reduction
Acid Halides to Alcohols: LiAlH4 Reduction
The mechanism proceeds in three steps. First, the nucleophilic hydride ion attacks the carbonyl carbon of the acid halide to form a tetrahedral intermediate. Next, the carbonyl group is re-formed, and the halide ion departs as a leaving group, generating an aldehyde. A second nucleophilic attack by the hydride yields an alkoxide ion, which, upon protonation, gives a primary alcohol as...

