Accelerated export and transportation of heavy metals in watersheds under high geological backgrounds

The geological background level of metals plays a major role in mineral distribution and watershed diffuse heavy metal (HM) pollution. In this study, field research and a distributed hydrological model were used to analyze the distribution, sources, and pollution risk of watershed HMs in sediments with high geological HM backgrounds. Study showed that the mineral distribution and landcover promoted the transport differences of watershed HMs from upstream to the estuary. And the main sources of Co, Ni, and V in the estuarine sediments were natural sources. Sources of Pb and Zn were dominated by anthropogenic sources, accounting for 76% and 64% of their respective totals. The overall ecological risk of anthropogenically sourced HMs was dominated by Pb (46.6%), while the contributions of Co and Ni were also relatively high, accounting for 35.70% and 33.40%. Moreover, redundancy analysis showed that HM variations in the sediments were most sensitive to soil erosion and mineralizing rock distribution. The spatial patterns of watershed HMs from natural sources were significantly influenced by P loading, precipitation, and forest distribution. This combination of experiments and model improves the understanding of watershed HM variation and provides a new perspective for formulating effective watershed HM management strategies.