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Distillation: Vapor–Liquid Equilibria01:01

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Distillation is a separation technique that takes advantage of the boiling point properties of disparate elements in a mixture. To perform distillation, we begin by heating a miscible mixture of two liquids with a significant difference in boiling points (at least 20°C). As the solution heats up and reaches the bubble point of the more volatile component, some molecules of the more volatile component transition into the gas phase and travel upward into the condenser, which is a glass tube...
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Various dissolution theories provide insight into the factors that influence the dissolution rate. Danckwerts' Model suggests that turbulence, rather than a stagnant layer, characterizes the dissolution medium at the solid-liquid interface. In this model, the agitated solvent contains macroscopic packets that move to the interface via eddy currents, facilitating the absorption and delivery of the drug to the bulk solution. The regular replenishment of solvent packets maintains the...
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Vapor Pressure02:34

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When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules move randomly about, they will occasionally collide with the surface of the condensed phase, and in some cases, these collisions will result in the molecules re-entering the condensed phase. The change from the gas phase to the liquid is called condensation. When the rate of condensation becomes equal to the rate of vaporization, neither the amount of the liquid nor the amount of the vapor...
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Phase Transitions: Vaporization and Condensation02:39

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The physical form of a substance changes on changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. Vaporization occurs when the thermal motion of the molecules overcome the intermolecular forces, and the molecules (at the surface) escape into the gaseous state. When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase...
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The vapor pressure of a fluid is a crucial concept in fluid mechanics, influencing phenomena such as boiling and cavitation. Vapor pressure refers to the pressure exerted by a vapor at a state of thermodynamic equilibrium with its corresponding liquid phase at a specific temperature. It represents the tendency of molecules to escape from the fluid surface into the vapor phase.
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Vapor Pressure Lowering03:28

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The equilibrium vapor pressure of a liquid is the pressure exerted by its gaseous phase when vaporization and condensation are occurring at equal rates:
 
Dissolving a nonvolatile substance in volatile liquid results in a lowering of the liquid’s vapor pressure. This phenomenon can be explained by considering the effect of added solute molecules on the liquid's vaporization and condensation processes. To vaporize, solvent molecules must be present at the surface of the solution....
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Updated: Jul 5, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
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An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids

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Nonequilibrium liquid-vapor interfaces: Linear and nonlinear descriptions.

Henning Struchtrup1, Hans Christian Öttinger2

  • 1Department of Mechanical Engineering, University of Victoria, Victoria, British Columbia, Canada V8W 2Y2.

Physical Review. E
|January 20, 2024
PubMed
Summary
This summary is machine-generated.

Local thermodynamic equilibrium may not apply to liquid-vapor interfaces under strong nonequilibrium conditions. New structural variables and interface temperatures are proposed for a broader thermodynamic description, impacting interfacial resistivities.

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Area of Science:

  • Thermodynamics
  • Interface Science
  • Non-equilibrium Physics

Background:

  • Local thermodynamic equilibrium is often assumed for liquid-vapor interfaces.
  • This assumption may fail under strong deviations from equilibrium.

Purpose of the Study:

  • To investigate the validity of local thermodynamic equilibrium for nonequilibrium interfaces.
  • To develop an extended thermodynamic description for interfaces under strong deviations from equilibrium.

Main Methods:

  • Applying Clausius-Clapeyron equations to bulk properties to define interface temperature.
  • Introducing structural variables to characterize interface states.
  • Analyzing the dependence of interfacial resistivities on interface temperature and fluxes.

Main Results:

  • A consistently defined interface temperature from bulk properties is close to the liquid bulk temperature.
  • An alternative interface temperature derived from surface tension differs significantly in strong nonequilibrium processes.
  • Interfacial resistivities are shown to depend on the interface temperature and mass/heat flux.

Conclusions:

  • The assumption of local thermodynamic equilibrium is not universally valid for liquid-vapor interfaces in nonequilibrium processes.
  • Structural variables and distinct interface temperature definitions are necessary for a more comprehensive thermodynamic description.
  • Understanding these factors is crucial for accurately modeling interfacial phenomena and transport properties.